White crystals forming on the LECA is either accumulated minerals or manufacturing residues. If they are acicular and make the pellets look “fuzzy”, it’s likely the latter. Either way, more humidity and/or more watering is a good idea.
Back in the days of PrimeAgra, the binders they used in manufacturing were sodium salts, so I added calcium nitrate and/or Epsom Salts to the soak water to “extract it faster”, figuring it would be a process similar to a water softener - salt coming out of the substrate, replacing the Ca and Mg in the water, but we dump the water and keep the now-fertilized substrate. Since then, I don’t know what binders are used by each manufacturer, just use plain water, and have found that length of soak with repeated water changes is more effective than any additive at extracting the residues.
I suspect the purer the soak water, the better, but I’ve always just used my well water in PA and municipal water here, which is pretty pure, aside from the lime they add to “sweeten” it.
I don’t know why one would add an acid. Every LECA I’ve ever seen, when soaked, yielded an initial pH between 5 & 7 in the soak water.
I was high on “Grow Stones”, as it was basically synthetic perlite made from recycled glass, but it was particularly alkaline, so they tried “passivating” the surface via an acid bath. That works, but only temporarily.